Polymeric reactive additives for repurposing mixed plastic waste
- Polymer compatibilizer
- Upcycling incompatible PET/POs blends
Polyethylene terephthalate (PET) and common polyolefins (POs), specifically polyethylene (PE) and polypropylene (PP), represent approximately 80% of plastic waste in the US. However, recycling rates for these materials are low due to challenges in separating mixed waste streams into pure recycle material streams and the inability to mix different polymer materials together to provide a functional plastic. Researchers at the University of Minnesota have developed hydroxy-terminated POs as reactive additives for compatibilizing commercial PET/PO binary blends. Weight percentages as low as 0.5% of these reactive additives yield functional plastic blends with increased fracture strength and toughness compared to blends without the additive. Additionally, these reactive additives do not require specialized manufacturing processes nor do they release volatile components. They have been shown to enhance melt-mixes of PET/POs blends using common plastic melt-mixing technologies such as extrusion.
Phase of DevelopmentTRL: 4-5
Polymeric reactive additives have been demonstrated to compatibilize PET/PE blends and are currently being optimized for PET/PP blends.
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- Christopher J. Ellison, PhD Professor, Department of Chemical Engineering and Materials Science
- Marc A. Hillmyer, PhD McKnight Presidential Endowed Chair, Department of Chemistry
- Zervoudakis, A. J.; Sample, C. S.; Peng, X.; Lake, D.; Hillmyer, M. A.; Ellison, C. J. (2022), Dihydroxy Polyethylene Additives for Compatibilization and Mechanical Recycling of Polyethylene Terephthalate/Polyethylene Mixed Plastic Waste, ACS Macro Lett., 18, 1396–1402
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